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Here are some useful websites for newbies:
The official POE forums have lots of good info. Theres build examples and shops.
Passive Skill Tree
Interactive skill tree. Lets you plan out your build without being in game. You should spend a bit of time here before you spend too many skill points.
Orb exchange rates
This give an approximate value for the different Orbs. You can use this to ballpark what an orb will trade for.
Gem exchange rates
This is a new site that gives the approximate value for the different gems. It includes gem quality which helps a lot for determining value.
Vendor Recipe list
Includes all the known vendor recipes. Recipes are sets of items that you can sell to the vendor to receive certain items. Example: One item with a Red, Green and Blue socket all linked together gives a Chromatic Orb.
Good source of all kinds of info. Go hear if you need more detailed info.
Edited by Waughoo, 05 March 2013 - 06:08 PM.